Chemical Concepts Demonstrated: Cr2+, Cr 3+, amd Cr (IV) oxidation states of chromium
Demonstration:
 
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Observations and Explanations:
| Dish | Observation / Explanation | 
| A + B | Violet solution of Cr(H2O)6 3+.  | 
  
| C | The color of the solution changes from violet to an "acid green".  | 
  
| D | Green Cr(OH)3 precipitates from the green solution. More base will cause the solid to redissolve to give a green chromite Cr(OH)4 -solution.  | 
  
| E | The green solution changes to orange as the CrO42-/Cr2O72- ions are formed.  | 
  
| E + HCl | After the HCl is added a series of erratic color changes are observed. When the reaction is complete the solution is green.  | 
  
| A, C, & D with HCl | Solution A remains violet. Solution C changes from green back to violet. Solution D produces another green solution.  | 
  
| B with HCl & Zn | When the solution becomes acidic, several pieces of Zn are added to the dish. The bright blue color of Cr2+ (aq) will be visible momentarily, but air oxidation rapidly converts this to a green solution.  | 
  
| Original solution + BaCl2 + Pb(NO3)2 | A yellow precipitate of BaCrO4 will form. Adding HCl will redissolve the precipitate and produce an orange-yellow solution. Pb(NO3)2 produces another yellow precipitate, PbCrO4.  |